Abstract
The phase composition of the M2O-ZnO-V2O5 (M = Li, Na, K, Rb, Cs) systems at subsolidus temperatures is investigated. Three groups of double vanadates are identified: M2Zn(VO3)4 for M = K, Rb, or Cs; M2ZnV2O7 for M = Na, K, or Rb; and MZnVO4 for M = Li or Cs. Double pyrovanadate Rb2ZnV2O7 is synthesized for the first time. Phase diagrams are designed for all systems. Comparative phase-formation features of the systems in the alkali oxide series are considered.
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