Abstract
The first experimental evidence that fullerenes react with alkali-metal trichloroacetates through a nucleophilic addition-substitution route, yielding dichloromethylenefullerenes as the final products, is reported. The intermediates, C60 (CCl3 )(-) and C70 (CCl3 )(-) anions, have been isolated in their protonated forms as ortho-C60 (CCl3 )H, as well as three ortho and one para isomer of C70 (CCl3 )H. The structures were unambiguously determined by means of (1) H, (13) C, and (1) H-(13) C HMBC NMR spectroscopy along with UV/Vis spectroscopy. The observed regiochemistry was analyzed with the aid of quantum chemical calculations. Conversion of the protonated compounds into the [6,6]-closed C60/70 (CCl2 ) cycloadducts under basic conditions can be effected only for the ortho isomers, whereas para-C70 (CCl3 )H decomposes back into pristine C70 .
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