Abstract
We report here reactions between the N-adamantyliminopyrolyl ligand 2-(AdN[double bond, length as m-dash]CH)-C4H3NH (L-H) and alkali metal hexamethyldisilazides [MN(SiMe3)2] (M = Li, Na and K) to afford the dimeric [{2-(AdN[double bond, length as m-dash]CH)-C4H3NLi(THF)}2] (1), [{2-(AdN[double bond, length as m-dash]CH)-C4H3N}{Na(THF)1.5}2] (2) and polymeric [{2-(AdN[double bond, length as m-dash]CH)-C4H3NK(THF)}n] (3) complexes at ambient temperature. A one-pot reaction between L-H, [KN(SiMe3)2] and alkaline earth metal diiodide (AeI2) in a 2 : 2 : 1 molar ratio, which resulted in the formation of a heteroleptic Ae metal complex [κ2-{2-(AdN[double bond, length as m-dash]CH)-C4H3N}2Ae(THF)2] [Ae = Mg (4), Ca (5)], is also reported. The solid-state structures of complexes 1, 3 and 4 were established through single-crystal X-ray diffraction analysis. The alkali and alkaline earth metal complexes 1-5 were utilised as precatalysts for the catalytic hydroboration of pinacolborane (HBpin) with aldehydes and ketones, and potassium complex 3 was identified as a competent catalyst under mild conditions. Additionally, cyanosilylation of carbonyl compounds was explored with trimethylsilyl cyanide and aldehydes/ketones, using the alkali metal precatalyst 3 under mild conditions. In both catalytic processes, the potassium catalyst 3 exhibited high tolerance towards a number of functional groups.
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