Aliphatic and polycyclic aromatic hydrocarbons in the bottom sediments from Klaipėda Harbour, Lithuania (Baltic Sea)

Abstract

ABSTRACTA total of 22 bottom surface sediment samples were collected from Klaipėda Harbour, Lithuania (Baltic Sea). Sediment parameters, such as grain size and concentrations of total organic carbon, aliphatic hydrocarbons (ALHs) and polycyclic aromatic hydrocarbons (PAHs), were determined. Hydrocarbon contamination levels in the sediments were estimated based on classifications provided in the literature, and potential biological effects were assessed based on the effects range low–effects range median values of the Sediment Quality Guidelines and on the total toxic benzo(a)pyrene equivalent. The results demonstrated that concentrations of PAHs and total aliphatic hydrocarbons in the sediments varied between 1.6 and 5456 ng g−1 d.w. and 6.9 and 727 μg g−1 d.w., respectively. In most cases, the concentrations of ALHs and PAHs in the sediments indicated low to moderate levels of pollution and were not observed to have any significant adverse effects on living biota. To determine possible sources of hydrocarbons, hydrocarbon compositions were analysed, and ALHs’ and PAHs’ specific diagnostic ratios were calculated. According to the results, the Klaipėda Harbour bottom sediments were dominated by PAHs of pyrogenic origin, whereas the origin of ALHs was mixed, that is, anthropogenic with a biogenic (aquatic and terrestrial) input.