Abstract

It is the aim of this study to discuss for two-body systems like homonuclear molecules in which eigenvalues and eigenfunctions are obtained by exact solutions of the solvable models based on SU(1, 1) Lie algebras. Exact solutions of the solvable Hamiltonian regarding the relative motion in a two-body system on Lie algebras were obtained. The U(1) ↔ O(2), U(3) ↔ O(4) and Uq(3) ↔ Oq(4) transitional Hamiltonians are employed to described for H2 and N2 molecules. Applications to the rotation-vibration spectrum for the diatomic molecule indicate that complicated Hamiltonian can be easily determined via the exactly solvable method. The results confirm the mixing of both vibrating and rotating structures in H2 and N2 molecules.

Highlights

  • The studies of molecular spectra of diatomic molecules are of great interest

  • The q-deformed vibron model of the diatomic molecules is reported by Alvarez et al in ref

  • We studied the phase transition of the even and odd nuclei based on q-deformed SU[1,1] algebraic model19,20

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Summary

OPEN Algebraic Study of diatomic

It is the aim of this study to discuss for two-body systems like homonuclear molecules in which eigenvalues and eigenfunctions are obtained by exact solutions of the solvable models based on SU[1, 1] Lie algebras. One has to employ some complicated numerical methods to diagonalize the transitional Hamiltonian in analytic and exact solvable solutions of the duality paring models in diatomic molecules at rotational and vibrational modes, but Pan et al in refs. We have defined the molecular spectra for diatomic molecules by using transitional Hamiltonians which are based on the affine SU[1, 1] algebraic technique and quantum deformation theory. The first reason is that it is a solvable model, a deformed version of the dynamical symmetries diatomic molecules has been constructed and we can have good accuracy in the study of energy spectra in the molecule The structure of this manuscript is as follows: section 2 briefly summarizes theoretical aspects of the transitional.

Theoretical framework
The correspondence between
EDunham vt νs
Numerical result
Conclusion
Author contributions
Additional information
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