Algal fouling and extracellular organic matter removal in powdered activated carbon-submerged hollow fiber ultrafiltration membrane systems

Abstract

In this work, the effect of powdered activated carbon (PAC) on fouling by algal solution during ultrafiltration using two different PAC dosing strategies: pre-depositing PAC onto the membrane surfaces or the conventional addition of PAC to the bulk feed. The addition of PAC by either mode improved the removal of extracellular organic matter (EOM) from the algal solution. However, for the pre-deposition mode, increasing the PAC amount from 0 to 2.1 g caused a steady increase in the membrane fouling rate (from 0.4 to 1.4 kPa/h), whereas the opposite result (from 0.4 down to 0.1 kPa/h) was found for the conventional PAC dosing mode. This is likely due to the differences in the initial arrangement of algal cells and PAC along the cake layer depths. The pre-deposited PAC avoided contact between cells and membranes, but aggravated the deformation of the cells and hindered their back-transport to the bulk solution. Furthermore, although the effect of PAC on the EOM fouling was marginal, there were highly synergistic effects when cells and EOM were present together in the PAC pre-deposition mode. Changes in the PAC dosing mode also altered the PAC-membrane interactions, inducing a higher cleaning efficiency of backwash for the conventionally-dosed PAC from membrane surfaces than that for the pre-deposited PAC.