Abstract

Gypsum is an excellent source of Ca and S, both of which are required for crop growth. Large amounts of by-product gypsum [Flue gas desulfurization gypsum-(FGDG)] are produced from coal combustion in the United States, but only 4% is used for agricultural purposes. The objective of this study was to evaluate the effects of (1) untreated, (2) short-term (4-year annual applications of gypsum totaling 6720 kg ha−1), and (3) long-term (12-year annual applications of gypsum totaling 20,200 kg ha−1) on alfalfa (Medicago sativa L.) growth and nutrient uptake, and gypsum movement through soil. The study was conducted in a greenhouse using undisturbed soil columns of two non-sodic soils (Celina silt loam and Brookston loam). Aboveground growth of alfalfa was not affected by gypsum treatments when compared with untreated (p > 0.05). Total root biomass (0–75 cm) for both soils series was significantly increased by gypsum application (p = 0.04), however, increased root growth was restricted to 0–10 cm depth. Soil and plant analyses indicated no unfavorable environmental impact from of the 4-year and 12-year annual application of FGDG. We concluded that under sufficient water supply, by-product gypsum is a viable source of Ca and S for land application that might benefit alfalfa root growth, but has less effect on aboveground alfalfa biomass production. Undisturbed soil columns were a useful adaptation of the lysimeter method that allowed detailed measurements of alfalfa nutrient uptake, root biomass, and yield and nutrient movement in soil.

Highlights

  • Gypsum is a common mineral in sedimentary environments [1], and has been used as an amendment on agricultural soils for over 250 years [2,3]

  • The production of gypsum in the US was stimulated as a result of the Clean Air Act Amendments of 1990, which mandated a reduction of 6.4 million tons of SO2 emissions by electricity utilities from 1990 to 2010

  • Measurements of exchangeable Ca and total S revealed that dissolution products of surface-applied gypsum had moved throughout the Brookston and Celina profiles compared with control treatment (CT) soils (Tables 1 and 2)

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Summary

Introduction

Gypsum is a common mineral in sedimentary environments [1], and has been used as an amendment on agricultural soils for over 250 years [2,3]. The production of gypsum in the US was stimulated as a result of the Clean Air Act Amendments of 1990, which mandated a reduction of 6.4 million tons of SO2 emissions by electricity utilities from 1990 to 2010. In the USA, more than 30 million Mg of FGDG was generated in 2014 [4]. Of this total, around 49% of FGDG produced was beneficially used in industrial applications, such as highway repairs [5], manufacturing of wallboard, and as a filler ingredient in some food products [6], a small fraction (4%, 1.2 million Mg) was used in agricultural applications, and the remainder FGDG was discarded as waste.

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