Abstract
The steroidal nitrone 7, N-oxy-N-demethyl-5α-20(N)-conenine, leads to an α-hydroxyl ester of hydroxylamine, to an α-substituted imine, or to an oxazirane, depending on the acid chloride used (benzoyl chloride or p-toluenesulfonyl chloride), and also on reaction conditions. These results offer additional information about the reaction of nitrones with acid chlorides.
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