Abstract

The GMOS (Global Mercury Observation System) project has the overall goal to develop a coordinated observing system to monitor mercury on a global scale. Here we present the long-term (2011–2020) air mercury monitoring data obtained at the Listvyanka station located at a shore of Lake Baikal, Siberia. The long-term monitoring shows obvious seasonal variation of the background mercury concentration in air, which increases in the cold and decreases in the warm season. The short-term anomalies are associated with the wind carrying the air from the industrial areas where several big coal-fired power plants are located. A positive correlation between the mercury, SO2 and NO2 concentrations is observed both in the short-term variations and in the monthly average concentrations. The analysis of forward and backward trajectories obtained with the HYSPLIT model demonstrates revealing of the mercury emissions sources. During the cruise of 2018, the continuous air mercury survey over Lake Baikal covered 1800 km. The average mercury concentration over Baikal is notably less in comparison with the average value obtained at the onshore Listvyanka station during the same days of the cruise. That can lead to the conclusion that Baikal is a significant sink of the atmospheric mercury.

Highlights

  • The GMOS (Global Mercury Observation System) project has the overall goal to develop a coordinated observing system to monitor mercury on a global scale to assess its emissions to atmosphere, transport, atmospheric chemistry, and deposition processes

  • The GMOS program included developing of the standard operational procedures (SOPs) for air mercury monitoring and mercury deposition assessment harmonized with the international standards, data acquisition and data quality management system, creation of a network of ground-based monitoring stations, periodic oceanographic cruises, and airborne measurements

  • One of such new points has been founded, as a secondary GMOS site, based on the Listvyanka monitoring station located at a shore of Lake Baikal, Siberia, far away from the existing mercury monitoring sites in Asia

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Summary

Introduction

The GMOS (Global Mercury Observation System) project has the overall goal to develop a coordinated observing system to monitor mercury on a global scale to assess its emissions to atmosphere, transport, atmospheric chemistry, and deposition processes. The GMOS program included developing of the standard operational procedures (SOPs) for air mercury monitoring and mercury deposition assessment harmonized with the international standards, data acquisition and data quality management system, creation of a network of ground-based monitoring stations, periodic oceanographic cruises, and airborne measurements. More than 40 ground-based stations in the Northern and Southern hemispheres were involved in the monitoring network covering many regions where little to no observational data were available before GMOS [1]. One of such new points has been founded, as a secondary GMOS site, based on the Listvyanka monitoring station located at a shore of Lake Baikal, Siberia, far away from the existing mercury monitoring sites in Asia. The monitoring station “Listvyanka” is located in a rural area of the southwestern coast of Lake Baikal (51.8467 N, 104.8930 E, 670 m a.s.l.) on the top of a coastal hill

Monitoring Site
Air Mercury Survey over Baikal
Determination of Particulate Bound Mercury
Seasonal Variations
Conclusions
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