AgTNP@TiO2@Ag core-satellite composites for sensitive sensing and in situ monitoring photodegradation of organic dyes by portable Raman spectrometer

Abstract

The development of sensitive, reliable, and robust substrates for surface-enhanced Raman spectroscopy (SERS) heavily relies on the creation of numerous hot spots. In this study, we propose a simple approach to fabricate core-satellite composites composed of AgTNP@TiO2@Ag, where Ag triangular nanoplates (AgTNPs) act as the cores, TiO2 serves as the interlayer, and Ag nanoparticles are deposited around them to form Ag satellites. By adjusting the amount of AgNO3, we precisely control the coverage of Ag nanoparticles on AgTNP@TiO2@Ag, thus fine-tuning their SERS sensitivity. Various characterization techniques were employed to examine their composition, morphology, and crystal structure. Thanks to the abundant hot spots created by the Ag satellites, these composites exhibit significantly enhanced SERS sensitivity and they demonstrate the capability to detect methylene blue (MB) at a concentration of 10−10 M by portable Raman spectrometer. Moreover, the AgTNP@TiO2@Ag composites effectively enable in situ SERS monitoring of the photodegradation reaction of MB. Overall, the novel AgTNP@TiO2@Ag composites prepared in this study exhibit high SERS sensitivity and excellent photocatalytic performance, making them highly valuable for environmental detection and ecological restoration purposes.