Agricultural bio-waste for removal of organic and inorganic contaminants from waste diesel engine oil

Abstract

Corncob, an agricultural bio-waste, was used as adsorbent to remove organic and inorganic contaminants in waste lubricating oil (WLO) from diesel engine. To improve its adsorption capacity, corncob was modified with mixed solution of nitric acid, Hexadecyl trimethyl ammonium bromide and ethanol. Characterization results showed the crystallinity index of corncob enhanced 12%, which would be ascribed to the disruption of the dense lignin-carbohydrates structure in lignocellulose biomass by modification. The surface of modified corncob became smoother and porous. The adsorption results showed modified corncob had better removal rates to contaminants than raw corncob. For WLO with 80,000 km mileage, the removal rates to Fe, Al, Cu were enhanced from 19%, 6.4%, 48–27%, 27%, 53%, while that for oxide, sulphate, aromates, soot and insoluble resins were enhanced 1.7, 1.2, 3.0, 1.7 and 1.7 times. The reduction rate of total acid number to WLO with 40,000, 60,000, 80,000 km were enhanced 16%, 9%, 12% by modified corncob, respectively. The optimal adsorption condition was explored as adsorbing 60 min at 90 °C with 2% adsorbent. Corncob, with the advantages of low cost, good biodegradability and high adsorption capacity, could be used as alternative to conventional adsorbent for WLO.