Abstract

Abstract The use of multiple detector size exclusion chromatography is described for the study of aging of pressure sensitive adhesive films based on styrene-isoprene-styrene block copolymers. In this preliminary investigation of thin films, room temperature oxidation resulted in the formation of an easily detected carbonyl chromophore. While the chromophore concentration was monitored with a UV detector on the chromatograph, the molecular weight distribution was measured with a differential refractometer. Several important general implications of this combination of detectors in SEC are described.

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