Aging of a New Niobium-Modified MAR-M247 Nickel-Based Superalloy

Abstract

MAR-M247 is a nickel-based superalloy that contains 3 wt.% Ta (weight percent of tantalum). Considering the chemical similarity between tantalum and niobium (Nb) and the lower cost of Nb, a modified MAR-M247 superalloy was produced with total replacement of Ta by Nb in this work. The samples were previously solutioned at 1260°C for 8 h and then aged at different times (between 5 and 80 h) and temperatures (between 780 and 980°C). The microstructures of the aged samples were characterized with a scanning electron microscope (SEM and FEG-SEM, both with EDS). Simulations of the MC carbide and γ′ fraction and the Ta and Nb content in both MC carbide and γ′ phase were performed with Thermo-Calc software (TT_Ni8 database) and simulations of the γ′ growth rate and γ′ mean diameter were performed with JMatPro software. MC carbide with high Hf content was observed in all the aged samples, in agreement with thermodynamic simulation results. The equilibrium γ′ fraction decreases from 67 mol.% at 780°C to 52 mol.% at 980°C. Good agreement between the calculated and experimentally determined γ′ particle size was also found. The growth rate of γ′ at 980°C is about 8 times higher than that at 780°C and 3 times higher than that at 880°C. The hardness values do not change considerably after aging at 780 and 880°C. However, these values decrease significantly after aging at 980°C.