Abstract

Epoxy primer coated aluminum alloys are artificially aged in three environments: UVA, UVA-neutral and UVA-acidic alternating-immersion. The corrosion morphology, corrosion products, electrochemical impedance, and molecular structure of the coated specimens are explored using SEM, EDS, EIS, and ATR-FTIR. The results demonstrate that the residual thicknesses of the primer decrease linearly under UVA-acidic alternating-immersion. The impedances of the coated specimens change in different ways in the three environments, which are influenced by the synergistic effect of the accumulation and dissolution of corrosion products, and post-curing of the primer. The degradation mechanisms and electrochemical equivalent circuits are analyzed at different stages.

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