Abstract
Two different coordination polymers are obtained from d10 metal ions [Zn(II) and Cd(II)] and N,N′-ethylenebisacetamide (EBA). {[Zn(EBA)1.5(NO3)] · (NO3)} n (1) is a 1-D coordination polymer assembled from zinc ions and EBA molecules acting as a bridging ligand. Cd(H2O)2Cl2(EBA) (2) is constructed from 1-D inorganic polymeric chains {Cd(OH2)2Cl2} n and uncoordinated N,N′-ethylenebisacetamide molecules. These chains are interconnected through hydrogen bonds resulting in a 3-D supramolecular network. The luminescent properties of the organic molecule EBA, as well as of the coordination polymers 1, and 2 have been investigated.
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