Abstract
We investigated coordination polymers of Ag+ with a cysteine-based thiol ligand designed to contain a tetraphenylethylene AIEgen (L- and D-1). The coordination polymers, forming in a variety of protic and aprotic organic solvents, such as THF, CH3CN and CH3OH, were shown to undergo aggregation in H2O/THF binary solvents at water volume fractions above 50%, where emission was substantially enhanced while the CD profile was reversed, yet the dependence of the CD signal on ee remained S-shaped for the polymers in the aprotic organic solvents THF and CH3CN, in contrast to that in protic solvents CH3OH and C2H5OH.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.