Ag(NH3)2]2SO4: A Strategy for the Coordination of Cationic Moieties to Design Nonlinear Optical Materials**

Abstract

AbstractOver recent decades, guided by the anionic group theory of nonlinear optical (NLO) materials, rational design strategies have been primarily focused on anionic moieties; consequently, structural modification and design of cationic moieties have long been neglected. Herein, we report a strategy for the coordination of cationic moieties that substantially enhances the optical properties of NLO materials. For an example with well‐known crystal structure, [Ag(NH3)2]2SO4, we demonstrate that the coordination of the Ag+ cation by the neutral ligand drives the formation of a noncentrosymmetric tetragonal P 21c structure as a positive uniaxial crystal. The bending of the [Ag(NH3)2]+ cationic moiety parallel to the z‐axis generates an anisotropic arrangement of the dipoles, i.e., a dipole of 0.12 D along the z‐direction, yet zero dipole in the xy‐plane, which interacts anisotropically with the incident light oscillating electromagnetic wave, leading to optical anisotropy with a large birefringence. The incident beam of 589.3 nm normal to the (110) crystal plane measures Δnobv.=0.08, and [Ag(NH3)2]2SO4 also exhibits a phase‐matching NLO response 1.4 times that of KH2PO4 (KDP) (obv. 1.4×KDP @1064 nm; cal. d36=1.50 pm V−1).