Ag nanoparticle decorated Sb2O3 thin film: synthesis, characterizations and application

Abstract

The property modifications in a thin film when its surface undergoes a nanoparticle decoration process in addition to its surface nanostructuring are investigated this paper. In specific, it describes the property modifications of antimony trioxide and its annealed variant, when their surface is decorated with Ag nanoparticles. Along with the modifications brought to the thin films, the morphology variations or agglomeration effects happening to Ag nanoparticles through/after this decoration process is also discussed here. We observe a mutual tuning of morphology as well as properties of thin film and nanoparticles. A fractal like cluster formation of Ag nanoparticle on the surface of nanostructured Sb2O3 thin film was witnessed. Whereas on the surfaces of Sb2O3 (annealed) thin film and glass plate, clustering of Ag nanoparticle is found to be different. On annealed Sb2O3 thin film surface, instead of forming fractal clusters most of the Ag nanoparticles fill in the voids between the thorns like structure of the film. The surface modification highly influences the optical absorption as well as the hydrophilicity of antimony trioxide samples. Due to the introduction of Ag nanoparticle, the absorption of Sb2O3 thin film in the visible region increased. All the synthesized films have roughness coefficient >1 and all are hydrophilic in nature. Nano structured Sb2O3 thin film is extremely hydrophilic and they become hydrophilic due to the introduction of Ag nanoparticle. The filling of Ag nanoparticles in the voids between the thorn structures might have prevented the water droplet penetration into these voids. Consequently, a partial wetting occurs on the film surface. High SERS efficiency factor (EF) and good reproducibility of Ag/Sb2O3/Glass make it a good candidate for SERS application.