Abstract

The effect of lead free glass frit compositions on the properties of thick film conductor and resistor pastes were investigated. Two types lead free frits, HBF-A(without <TEX>$Bi_2O_3$</TEX>) and HBF-B(with <TEX>$Bi_2O_3$</TEX>) were made from <TEX>$SiO_2$</TEX>, <TEX>$B_2O_3$</TEX>, <TEX>$Al_2O_3$</TEX>, CaO, MgO, <TEX>$Na_2O$</TEX>, <TEX>$K_2O$</TEX>, ZnO, MnO, <TEX>$ZrO_2$</TEX>, <TEX>$Bi_2O_3$</TEX>. And Ag based conductor pastes and <TEX>$RuO_2$</TEX> based resistor paste were prepared by mixed with these frits and functional phase(Ag and <TEX>$RuO_2$</TEX>), and organic vehicle. The properties of thick film conductor and resistor sintered at <TEX>$850^{\circ}C$</TEX> were studied after printing on <TEX>$Al_2O_3$</TEX> substrate. The morphology of the sintered films surface were SEM and EDS were carried out to analysis the chemical composition on resistor surface and state of Ru atom in frit matrix.

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