Abstract
Abstract. This study focuses on the aerosol hygroscopic properties as determined from ground-based measurements and Mie theory. Usually, aerosol ground-based measurements are taken in dry conditions in order to have a consistency within networks. The dependence of the various aerosol optical characteristics (e.g. aerosol absorption, scattering, backscattering or extinction coefficients) on relative humidity has therefore to be established in order to determine their values in the atmosphere, where relative humidity can reach high values. We calculated mean monthly diurnal values of the aerosol hygroscopic growth factor at 90% relative humidity GF(90) based on measurements performed at the atmospheric research station in Ispra (Italy) with a Hygroscopicity Tandem Differential Mobility Analyzer over eight months in 2008 and 2009. Particle hygroscopicity increases with particle dry diameter ranging from 35 to 165 nm for all seasons. We observed a clear seasonal variation in GF(90) for particles larger than 75 nm, and a diurnal cycle in spring and winter for all sizes. For 165 nm particles, GF(90) averages 1.32 ± 0.06. The effect of the particle hygroscopic growth on the aerosol optical properties (scattering, extinction, absorption and backscatter coefficients, asymmetry parameter and backscatter faction) was computed using the Mie theory, based on data obtained from a series of instruments running at our station. We found median enhancement factors (defined as ratios between the values of optical variables at 90% and 0% relative humidity) equal to 1.1, 2.1, 1.7, and 1.8, for the aerosol absorption, scattering, backscattering, and extinction coefficients, respectively. All except the absorption enhancement factors show a strong correlation with the hygroscopic growth factor. The enhancement factors observed at our site are among the lowest observed across the world for the aerosol scattering coefficient, and among the highest for the aerosol backscatter fraction.
Highlights
Atmospheric aerosol particles reveal changes in their microphysical and optical properties with relative humidity (RH) due to the water uptake
We studied the diurnal and seasonal variations in the atmospheric aerosol growth factor at 90 % RH, focusing on the data obtained in January, May, July and October as representative for each season
Aerosol hygroscopicity in terms of hygroscopic growth factor and enhancement factors of the main optical properties was determined based on measurements performed at the station for atmospheric research in Ispra and Mie calculations
Summary
Atmospheric aerosol particles reveal changes in their microphysical and optical properties with relative humidity (RH) due to the water uptake. These changes depend on the particles’ chemical composition and size. In order to determine the properties of the aerosol in ambient conditions, corrections have to be applied to all the parameters measured in dry conditions. These corrections are mandatory once we need to compare these in-situ measurements with other measurements taken at ambient conditions (e.g. from satellite-borne or ground-based active or passive remote sensing devices). The aerosol optical parameters (aerosol scattering, absorption and backscatter coefficient) at ambient RH represent the input to the radiative transfer models to determine the direct aerosol climate forcing (e.g. Chylek and Wong, 1995)
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