Abstract
The catalytic system made up of cobalt(II) acetylacetonate, 2-methylpropanal and dioxygen (or air) facilitated the oxidative cleavage of (1 S,2 S,3 R,5 S)-(+)-pinanediol 1a and (1 R,2 R,3 S,5 R)-(−)-pinanediol 1b to enantiomerically pure cis-pinonic acids 4a–b.
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