Abstract

Abstract The surface tension, pH and contact angle of the wetting liquid as well as the complex composition of the leaf surface are important parameters to describe the spreading, wettability and absorption of agrochemicals on the leaf surfaces. The contact angle of aqueous solutions of agrochemicals (multi-micronutrient fertilizers, growth regulator and insecticides) with/without Leaf guard, bis(2-ethylhexyl) sulfosuccinate sodium salt (AOT) and Sapindus mukorrossi (Ritha) were measured over the surface of mango leaves. The order of contact angle (mean) values was found to be AOT < Ritha < Leaf guard, which implies that AOT is a better wetting agent, but Ritha has a higher range of adhesion work because of its acidic nature (low pH). The wetting free energy was found to be more negative in the presence of Leaf guard, Ritha and AOT than in water, which indicates that wetting is more spontaneous in the presence of surfactants. The adaxial surface of mango leaves had a higher surface free energy than the abaxial part and hence showed higher wettability than the abaxial part.

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