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Abstract
Sulphur tetrafluoride has been known since 1958 as an efficient fluorinating agent for replacing oxygen atoms in carbonyl groups by fluorines. In the past fifteen years a number of new reactions of sulphur tetrafluoride with carbonyl compounds have been discovered. These include formation of bis(1,1-difluoroalkyl) ethers from alkanecar☐ylic acids, bis(1-fluoroalkyl) ethers from aliphatic aldehydes, and cyclic fluoroethers from difunctional car☐ylic acids and aldehydes. In the reactions with branched aldehydes rearrangements of hydrogen and fluorine atoms and also of the carbon skeleton were observed. Tertiary amides were successfully converted to 1,1-difluoroamines and tertiary formamides to trifluoromethylamines. This last reaction involves simultaneous fluorination of the carbon-oxygen and carbon-hydrogen bonds.Participation of carbocations in the mechanism of fluorination of carbonyl groups has been proved and a revised mechanism proposed. Evidence for a reduction-oxidation mechanism for the replacement of formyl hydrogen by fluorine has also been found.
Published Version
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