Abstract

Tungsten oxide-based materials have drawn huge attention for their versatile uses to construct various energy storage devices. Particularly, their electrochromic devices and optically-changing devices are intensively studied in terms of energy-saving. Furthermore, based on close connections in the forms of device structure and working mechanisms between these two main applications, bifunctional devices of tungsten oxide-based materials with energy storage and optical change came into our view, and when solar cells are integrated, multifunctional devices are accessible. In this article, we have reviewed the latest developments of tungsten oxide-based nanostructured materials in various kinds of applications, and our focus falls on their energy-related uses, especially supercapacitors, lithium ion batteries, electrochromic devices, and their bifunctional and multifunctional devices. Additionally, other applications such as photochromic devices, sensors, and photocatalysts of tungsten oxide-based materials have also been mentioned. We hope this article can shed light on the related applications of tungsten oxide-based materials and inspire new possibilities for further uses.

Highlights

  • Energy exhaustion and environment deterioration has caused more and more scientific and public concern

  • The results showed that slight doping of Nb enables the film to have wider optical modulation range, shorter switching speed, and higher capacitance because the introduction of the Nb element was accompanied by the introduction of O vacancy which increased the conductivity of the electrode

  • Tungsten oxides are attractive for their numerous possibilities in various fields, in energy storage like lithium ion battery (LIB), SCs, and electrochromisms

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Summary

Introduction

Energy exhaustion and environment deterioration has caused more and more scientific and public concern. When used as the electrode in SC, because the valence of W can be changed between +2 and +6, its theoretical specific capacity is 1112 F g−1 [26], much higher than the normally used double-layer capacitor’s carbon electrode material, and when as the anode in LIB, its theoretical specific capacity is 693 mA h g−1 , nearly double that of graphite They are endowed with other advantages including high density, low cost, environmental friendliness, and nontoxicity. We can get direct information about their working condition from color signals, bringing us great convenience and safety, or we can see it as a transparent battery and make good use of the energy stored in it, reducing electricity consumption These bifunctional devices can have more possibilities by integrating other parts, such as solar cells, so that self-powered systems are achieved [30,31].

The Crystal Structure of Tungsten Oxides
WO3 Electrode Materials of Supercapacitors
Single Phase WO3 Nanostructures
Multi-Phased
Tungsten Oxide-Based Materials as Anodes in Lithium Ion Battery
Non-Stoichiometric Tungsten Oxides
Nano-Structured
Tungsten Oxide-Carbon Composites
Tungsten
Inverse
IO structure on the ITO coated base after removing
Dynamic
Electrochromic
Tungsten Oxides Based ECESDs
Method
Solar Cell and Tungsten Oxide-Based EC Integrated Multifunctional Devices
Other Applications of TungstenofOxides-Based
Findings
Summary and Outlook
Full Text
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