Abstract
The transition-metal catalyzed coupling reaction is one of the versatile methods for the generation of new carboncarbon bonds in organic synthesis, and it has become a hot topic in current organic chemistry. Transition metal salts and their complexes were used as catalyst directly in the classic methods with the drawbacks of high cost of the transition metal, the metal contamination of the product and the toxicity remained. In order to overcome these problems, developing green synthetic methods based on efficient and reusable catalytic systems is more desirable in organic synthesis. In this paper, the recent progress on the carbon-carbon coupling reactions catalyzed by the supported transition-metal catalysts has been reviewed.
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