Abstract

A robust, near-infrared (NIR) active photothermal agent, CNTs-PAMAM/G4-CdS, is designed by covalent grafting of fourth generation poly(amidoamine) (PAMAM) to carbon nanotubes (CNTs) and successive deposition of cadmium sulfide (CdS) nanocrystallites. The systematic advancement in photothermal effect of CNTs was achieved by grafting of first, second, third, and fourth generation PAMAM through the repeated process of Michael's addition. The subsequent deposition of CdS nanocrystallites over fourth generation PAMAM grafted CNTs has further improved the photothermal effect (PTE) of CNTs. The photothermal effect of CNTs-PAMAM/G4-CdS was accessed by illuminating with 980 nm NIR laser. During measurement of PTE, maximum temperature attained by CNTs-PAMAM/G4-CdS was 64.1 °C which far exceeds the survival temperature of cancer cells. The photothermal conversion efficiency estimated for CNTs-PAMAM/G4-CdS was 32%, which is higher than the value reported for popular gold and copper based photothermal agents. Apart from its outstanding photothermal effect, CNTs-PAMAM/G4-CdS possessed excellence in both antiphoto-bleaching and antiphoto-corrosiveness.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.