Abstract
Abstract Zn/Cr layered zinc hydroxide materials with different molar ratios of Cr/Zn have been synthesized through the coprecipitation method at pH of 9.0–9.5. At high Cr/Zn molar ratios of 0.5/1–1/3, the materials possess some layered structure with carbonate anions between the interlayer galleries. The catalysts present uniform particle sizes and quite high surface area. An isomorphous substitution of Zn 2+ by Cr 3+ in the brucite-like sheets makes the layered Cr-doped zinc hydroxides potential catalysts for efficient oxidation of rhodamine B with H 2 O 2 solution. The experimental results indicated that the intra-lattice Cr 3+ ions are more active than Cr 2 O 3 components in the oxidative removal of rhodamine B. The degradation efficiency is dependent on the intra lattice Cr 3+ contents and reaction variables. The Cr/Zn LDH gave a high decolorization (99%) of rhodamine B at near neutral pH and room temperature.
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