Abstract

Abstract Over the last decade, nickel nanoparticles (NiNPs) have been investigated for various potential applications due to their superior ferromagnetic properties such as magneto-crystalline anisotropy, high coercive forces, and chemical stability. Therefore, there has been a tremendous enhancement in the synthesis techniques, proposed reaction mechanisms, and applications of NiNPs. This paper presents a recent overview of the synthesis, reaction mechanisms, and applications of NiNPs. NiNPs in the size range of 1–100 nm are synthesized by various methods for research and commercial applications. The synthesis techniques are classified into three main types, namely, top-down, bottom-up, and hybrids of top-down and bottom-up protocols including solvothermal, physical, and chemical approaches. The detailed reaction mechanisms in the formation of NiNPs, especially for biosynthesis techniques, are extensively described. Trends in NiNP applications in fields such as biomedical, catalysis, supercapacitors, and dye-sensitized solar cells are explored. The basic advantages and role of NiNPs as a catalyst for various reactions are illustrated here.

Highlights

  • In the last decade, nanotechnology has broadened the scope for researchers, producers, and consumers in almost all sectors by enabling the engineering of functional systems at the nanoscale level mostly in the form of nanoparticles [1]

  • The results showed that the Ni nanoparticles possess an enhanced anti-inflammatory and larvicidal activity when compared to the crude leaf extract

  • Terpenoids play a significant role in the biosynthesis of silver ions to metallic nanoparticles when Geranium leaves extracts are used in the reactions; the major terpenoid of Cinnamomum zeylanisum is eugenol, which was found to be involved in the bio-reduction of HAuCl4 as well as AgNO3 to nanomaterial [91]

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Summary

Introduction

Nanotechnology has broadened the scope for researchers, producers, and consumers in almost all sectors by enabling the engineering of functional systems at the nanoscale level mostly in the form of nanoparticles [1]. Advanced nickel nanoparticles technology: from synthesis to applications 1457 and nickel–iron alloys [7] These reviews did not focus on NiNPs; they discussed nickel oxides and alloys. There is the need for thorough analyses of synthesis, reaction mechanisms, and applications of NiNPs. The synthesis of Ni nanoparticles has often been associated with various challenges. NiNPs must be characterized immediately after production to avoid conversion to Ni compounds like oxides and hydroxides These factors must be taken into consideration in planning the synthesis of Ni nanoparticles [28]. The present study was designed to analyse recent synthesis, reaction mechanisms, and applications of Ni nanoparticles as well as the specific advantages of using Ni as a catalyst. The scope of this study will be limited to addressing the applications of Ni nanoparticles in various fields of nanotechnology, science, and biomedical sciences as well as to discuss the specific advantages of Ni nanoparticles as catalysts in reactions, as compared to other magnetic nanoparticles

Techniques for the synthesis of NiNPs
Mechanical milling
Laser ablation
Thermal decomposition
Nanolithography
Sputtering technique
Sol–gel technique
Spinning fabrication
Pyrolysis technique
Biosynthesis
Synthesis of Ni nanoparticles using leaf extracts as reducing agent
Synthesis of Ni nanoparticles using microorganisms as reducing agent
Mechanisms of Ni nanoparticle formation involving terpenoids
Mechanisms of Ni nanoparticle formation involving flavonoids
Mechanisms of Ni nanoparticle formation involving amino acids
Solvothermal synthesis of Ni nanoparticles
Fabrication of Ni nanoparticles by arc discharge method
Production of Ni nanoparticles by microwave combustion technique
Biomedical applications of Ni nanoparticles
Applications of Ni nanoparticles as catalyst
Application of Ni nanoparticles in dyesensitized solar cells and sensors
Tabulation of other applications of NiNPs
The advantages of using Ni as catalyst
The advantages of Ni nanoparticles as a cheap catalyst
Advantages of using Ni catalyst in Suzuki-Miyaura reactions
Advantages of using Ni nanoparticle due to its various oxidation states
Conclusion
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