Advanced Fabrication and Characterization of Hydrothermal Responsive Fabric from Microcrystalline Cellulose-Reinforced Shape Memory Polyurethane Filament

Abstract

Demands for smart textiles have recently increased quickly in terms of functionality and responsiveness to wearers and environmental changes. This paper explores the development of hydrothermal responsive shape memory woven fabric from Microcrystalline Cellulose Reinforced Shape Memory Polyurethane Microcomposite Filament. The concentration of microcrystalline cellulose and drawing ratio of the filaments were first optimized according to the tensile strength and shape recovery ratio and taken as 15 wt% and 2.0 respectively. Hydrothermal responsive shape memory micro-composite filaments were then produced from shape memory polyurethane (SMPU) and microcrystalline cellulose (MCC) with optimized concentration and draw ratio by wet spinning process. The physical, mechanical, thermal and shape memory performances of the filaments were studied. The optimized filament was found to have a tensile strength of 0.91 cN/dtex and elongation of 385.2% in which the strength is much more improved when compared to a pure SMPU filament of strength 0.72 cN/dtex. The shape fixity and shape recovery results of the micro-composite filament were found to be 71.2% and 93.6% respectively. A woven fabric was manufactured from pure polyester, cotton as warp and SMPU-MCC filaments as weft and its breathability and shape memory properties were investigated. The air permeability of SMPU-PE fabrics was found to be 172.9 mm/s and 155.1 mm/s in its fixed temporary shape and recovered shape respectively. The water vapour permeability of SMPU-CT fabric was found to be 612.01 g/m2.h and 540.28 g/m2.h in its fixed temporary and recovered shape respectively which shows smart breathable fabrics can be made and adopted with enhanced properties.