Adsorptive reduction of water hardness by a highly porous and regenerative geopolymer fabricated from coal fly ash waste with low-temperature calcination

Abstract

In this research paper, potassium-activated geopolymer cubes (GeoC) fabricated from waste coal fly ash with low-temperature calcination were investigated as a water softening agent. The GeoC reduced water hardness contents by adsorbing calcium (Ca2+) and magnesium (Mg2+) ions from aqueous solutions. Batch experiments were conducted to investigate the adsorption performance for Ca2+ and Mg2+, including contact time, initial concentration of cations, and interference with competitive cations. The best performance for water hardness adsorption was found on GeoC-35, fabricated with the highest silicate ratio to hydroxide. The adsorption process reached equilibrium after a contact time of 6 h for Ca2+ and 24 h for Mg2+. The maximum adsorption capacity for Ca2+ and Mg2+ was 52.0 and 17.3 mg/g, respectively. Langmuir and pseudo-second-order models fitted the experimental data well, indicating that chemical reactions occurred on a homogeneous surface. The GeoC can also be reused for removing hardness. Furthermore, the increase in potassium and silicon concentration in solution varied directly with removal efficiency, suggesting that the aluminosilicate framework played a role in reducing water hardness via cationic exchange. The presence of competitive cations decreased adsorption ability, albeit it still exhibited an appreciable removal performance.