Adsorptive potential of iron oxide based nanocomposite for the sequestration of Congo red from aqueous solution

Abstract

The ability of polypyrrole-Iron oxide-seaweed nanocomposite has been tested for the removal of congo red from aqueous solution. The characteristics of nanocomposite after adsorption of Congo red (CR) have been analyzed. FTIR results authorized the involvement of various functional groups in the adsorption of CR. The change in morphology of nanocomposite was analyzed using scanning electron microscope (SEM). TEM and BET analysis were performed to characterize the nanocomposite. The effect of various parameters namely pH, adsorbent dosage, initial dye concentration, adsorption time and temperature are studied. The optimum condition for the effective removal of CR are: pH-3, initial CR concentration- 40 mg/L, nanocomposite dosage- 20 mg, contact time-40 min and temperature-40οC. Adsorption isotherm studies and kinetic studies were done. Langmuir isotherm fits with the experimental data very well with high coefficient of determination (R2 = 0.98) and maximum dye uptake of 500 mg/g is reported. In kinetic studies, pseudo second order model was obeyed (R2 = 0.994). Thermodynamic properties were determined and found that the nature of process is spontaneous, endothermic and increased in randomness. The mechanism of sorption was proposed. Desorption studies were carried out and showed that the nanocomposite could be effectively reused up to five cycles. Thus the outcomes proved that the polypyrrole-iron oxide-seaweed nanocomposite to be an operative, recyclable and low-cost adsorbent for the treatment of dye bearing water.