Adsorptive exclusion of crystal violet dye using barium encapsulated alginate/carbon composites: characterization and adsorption modeling studies.

Abstract

The present study is devoted to the removal of crystal violet dye using the synthesized barium alginate/carbon composites abbreviated as BA (barium alginate), BAAC (barium alginate/activated carbon), BASC (barium alginate/starch carbon), and BASSC (barium alginate/starch carbon modified with CTAB). The adsorptive removal of crystal violet as a function of contact time, pH of solution, composite dose, initial dye concentration, and temperature was studied. The uptake of crystal violet (CV) dye for the composites was recorded in the range of 36 mg g-1 to 50 mg g-1 at pH 8.03 ± 0.03 for an equilibrium time of 120 min. The adsorption kinetics and isotherms in compliance with the CV sorption onto BA/carbon composites corroborated the utmost fit of pseudo-second-order and Freundlich isotherm models, respectively. The recycling process was achieved using the barium alginate-treated bead carbons for different initial CV dye concentrations of 10-30 mg L-1 with a scope of zero disposal. The practicability of BA/carbon composites in a groundwater sample spiked with 30 mg L-1 of CV was successfully achieved with a removal efficiency of about 65-74%. Characterization studies for the composites using FTIR, SEM (with EDS), XRD, TGA, and BET were carried out and discussed in the paper.