Abstract
Differential and integral molar entropies of the adsorbed layer are calculated from the dependence of the coverage on pressure and temperature published in part I. The experimental entropies correspond up to coverages of 2 × 10 14 molecules cm −2 with entropies of the localized adsorption and an additional vibration entropy of about 20 cal deg −1 mole −1 caused by vibrations of the adsorbed atoms in the order of magnitude of 10 12 sec −1. At higher coverages the entropy increases and passes through a maximum. This is explained by the formation of a second adsorption state (γ state) probably consisting of molecular hydrogen.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
