Adsorption removal of ibuprofen and naproxen from aqueous solution with Cu-doped Mil-101(Fe)

Abstract

Due to the excellent anti-inflammatory effect, ibuprofen and naproxen have been widely used in the people's daily life, which inevitably leads to their pollution in natural water environment. The removal of these chemicals from water has drawn great interests. Here, a new Cu-doped Mil-101(Fe) was synthesized through a one-step solvothermal method and successfully applied for the adsorption removal of ibuprofen and naproxen from water. A series of characterization techniques (FESEM, TEM, N2 adsorption-desorption analysis, XRD and FT-IR) were applied to explore the physicochemical properties of the prepared Cu-doped Mil-101(Fe). The adsorption performances of the Cu-doped Mil-101(Fe) for ibuprofen and naproxen, including the adsorption kinetics and isotherms, and effects of diverse influencing factors (pH, ionic strength, and natural organic matter) were examined through batch experiments. The adsorption kinetics and isotherms of ibuprofen and naproxen on the Cu-doped Mil-101(Fe) fitted well with the pseudo-second-order model and Langmuir model, respectively. The maximum adsorption capacities of Cu-doped Mil-101(Fe) were 497.3 and 396.5 mg/g for ibuprofen and naproxen, respectively. The pH of solution in a range of 3-9 exerted no significant effects on the adsorption process. The adsorption was almost unaffected by the ionic strength and humic acid. The π-π interaction and hydrogen bond interaction between the adsorbent and adsorbates were found to be accountable for adsorption. The Cu-doped Mil-101(Fe) was readily regenerated by ethanol and could be repeatedly used.