Abstract
Hazardous effluents from textile industries being major contributors of water pollution and impose potential adverse effects on environment. In present study, Fe3O4 embedded oxidized Sterculia gum/Gelatin hybrid matrix have been fabricated and evaluated for enrichment of methyl orange (MO) and methylene blue (MB). Newly synthesized matrix was characterized through powdered XRD, FTIR, FESEM, TEM and TGA. Integrated nanoparticles improved dye enrichment and facilitated removal of matrix from the aqueous solution under the influence of magnetic field. Influence of various reaction parameters viz.: contact time, adsorbent dose, initial dye concentration, temperature & pH of the adsorption medium on dye enrichment have been evaluated. Maximum adsorption (90 % and 88 % for MO and MB respectively) has been achieved. Langmuir, Freundlich and Tempkin adsorption isotherms have been evaluated. Experimental results validate well fitted Freundlich isotherm for MO and Temkin isotherm for MB. Adsorption kinetics has been analyzed through Pseudo first order, second order kinetic and intra particle diffusion models. Adsorption of both dyes was best explained via pseudo second order kinetic model. Negative value of Gibb's free energy change (−26.487 KJ mol −1 and − 24.262 KJ mol −1) for MB and MO at 303 K was an indication of spontaneity of the reaction.
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