Abstract
The biosorption is an effective and economical method to deal with the wastewater with low concentrations of uranium. In this study, we present a systematic investigation of the adsorption properties, such as the kinetics, thermodynamics, and mechanisms, of modified rice stems. The rice stems treated with 0.5 mol/L NaOH solutions show higher removal percentage of uranium than those unmodified under the conditions of initial pH (pH = 4.0), absorbent dosage (5–8 g/L), temperature (T = 298 K), and adsorption equilibrium time (t = 180 min). The removal percentage of uranium(VI) decreases with increasing initial concentration of uranium(VI). The Langmuir isotherm model, which suggests predominant monolayered sorption, is better than Freundlich and Temkin models to elucidate the adsorption isotherm of adsorbed uranium. Kinetic analyses indicate that the uranium(VI) adsorption of the modified rice stem is mainly controlled by surface adsorption. The pseudo-second-order kinetic model, with the correlation coefficient of R2 = 0.9992, fits the adsorption process much better than other kinetic models (e.g., pseudo-second-order kinetic model, Elovich kinetic model, and intraparticle diffusion model). The thermodynamic parameters ΔG0, ΔH0, and ΔS0 demonstrate that the adsorption of uranium(VI) is an endothermic and spontaneous process, which can be promoted by temperature. The adsorption of uranium can change the morphology and the structure characteristics of the modified rice stem through interaction with the adsorption sites, such as O-H, C=O, Si=O, and P-O on the surface.
Highlights
Uranium is a heavy metal with significant chemical toxicity and radioactivity
Large amounts of uranium released from aqueous solutions of natural deposits, uranium mill tailings, and ammunition shave migrated into the environment [1, 2]
The rice stem is chosen to deal with the wastewater with low contents of uranium. e main aim of this study is to investigate the effects of different experimental conditions, such as modified methods, pH, adsorbent dose, initial concentration, sorption equilibrium time, and temperature
Summary
Uranium is a heavy metal with significant chemical toxicity and radioactivity. Since the leakage of radio nuclides in the Japan’s Fukushima Daiichi nuclear plant, the uranium contamination has attracted more and more attentions. Erefore, it is critically important to prevent the uranium of wastewater from transporting into the environment Many methods, such as chemical precipitationcrystallizing, ion exchange, solvent extraction, and film separation [4,5,6,7,8,9], have so far been developed to deal with the uranium-containing wastewater. These methods are not effective and economical, especially when treating large amounts of wastewater containing the low contents of the radioactive ionic material [10]. Our study suggests that the modified rice stem is a kind of promising biosorbent material to efficiently and economically remove uranium(VI) from the wastewater
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