Abstract
The variation of interfacial tension of a solution with surfactant concentration in bulk can be used, in conjunction with the Gibbs adsorption equation, to probe the behaviour of adsorbed surfactant monolayers. An adsorption isotherm equation expresses the relationship between bulk and surface concentrations of surfactant, and is used to determine thermodynamic quantities of surfactant adsorption. The variation of the surface pressure of a surfactant monolayer with the surface concentration is described by a surface equation of state, which reflects something of the nature of a monolayer. The way in which inorganic electrolytes modify the adsorption and monolayer behaviour of ionic surfactants is explained, and adsorption from surfactant mixtures is also introduced. In the Appendix, the discussion is extended to the treatment of adsorbed monolayers as two-dimensional solutions of surfactant with solvent molecules, rather than as two-dimensional gases.
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