Abstract

High phosphate concentrations in natural waters are associated with eutrophication problems that negatively affect the fauna and flora of ecosystems. As an alternative solution to this problem, we evaluated the adsorptive capacity of the fruit peel ash (PPA) of Caryocar coriaceum Wittm and its efficiency in removing phosphate (PO43-) from aqueous solutions. PPA was produced under an oxidative atmosphere and calcinated at 500°C. The XRF and EDS analyses of PPA after contact with an aqueous PO43- solution showed an increase in its PO43- content, thus confirming the adsorption of PO43-. The Elovich and Langmuir models are the ones fitting the kinetics and the equilibrium state of the process, respectively. The highest PO43- adsorption capacity was approximately 79.50mgg-1 at 10°C. PO43- adsorption by PPA is a spontaneous, favorable, and endothermic process involving structural changes. The highest removal efficiency was 97.08% using a 100mg.L-1 PO43- solution. In sight of this, PPA has shown potential as an excellent natural bioadsorbent.

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