Abstract
SummaryAn explanation is put forward for the shape of adsorption envelopes found for phosphate adsorption by various metallic oxides. The equation xm= C1 (μH3PO4+μ∑anions) is proposed, where μH3pO4 is the chemical potential of undissociated H3PO4; μ∑anions is the chemical potential of all phosphate anions considered as one. component; C1 is a constant that includes influences of surface charge, chemical affinity of the metal for phosphate, specific surface area, etc., and xmis the calculated Langmuir maximum adsorption of P at each pH. The dependence of C1 on the metal present in the oxide is shown.
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