Abstract

The thermodynamic characteristics of adsorption of isomeric molecules of 1,1′-, 1,2′-, and 2,2′-diadamantanes, 1- and 2-phenyladamantanes, and 1-cyclohexyladamantane on the surface of graphitized thermal carbon black (GTC) were experimentally determined. The influence of the molecular structure of adsorbates on their adsorption on the basis face of graphite was considered. A high selectivity of the GTC surface for the gas chromatographic separation of mixtures of the considered structural isomers was shown.

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