Adsorption of hexavalent chromium using Water Hyacinth Leaf Protein Concentrate/Graphene Oxide hydrogel.

Abstract

Water Hyacinth Leaf Protein Concentrate/Graphene Oxide (WHLPC/GO) hydrogel was synthesized for the removal of Cr(VI) from wastewater. About 90% of the prepared hydrogel constitutes WHLPC. The prepared material was characterized by FT-IR and XRD. The process variables such as pH, contact time, adsorbentdosage, initial Cr(VI) concentration, and temperature were optimized using a batch mode experiment. Kinetic studies were alsoconducted and it was observed that the chemosorptive pseudo-second-order best described the adsorption system with a correlation coefficient(R2) of 0.984. The highest adsorption capacity of 322.00 mg/g was achieved at pH 1.0, and equilibrium was achieved within 420 min. Various isotherm models were analyzed using non-linear fitting. It was found that the Sips model provides the best fit, indicating heterogeneous and uniform active site surface adsorption of Cr(VI) on the WHLPC/GO. The reuse efficiency of the synthesized material was also found to be greater than 84% for five consecutive cycles. Thermodynamic studies were conducted and results revealed that the adsorption was spontaneous and endothermic.