Abstract
The adsorption of hexachloroplatinic acid on γ-Alumina coatings is investigated in order to prepare monolithic structure catalysts for carbon monoxide oxidation. For acid concentrations in the range 0.25-1.5 mM the adsorption is examined in a batch process and a kinetic model is proposed and evaluated. The pH of the solution has a major impact on the adsorption rate and dispersion of Pt on Al2O3 and when acidity becomes lower than 1.5 pH value the deposition of Pt on the catalyst by pore volume impregnation is favourable. The catalytic properties of Pt-alumina as oxidation catalyst for CO depend strongly on the adsorption rate of H2PtCI6. A difference of 80 °C at the light off temperature is observed for catalysts prepared by adsorption from solutions with different acidity.
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