Adsorption of chromium from electroplating wastewater using activated carbon developed from water hyacinth

Abstract

Industrial wastewater polluted with high concentrations of Cr is commonly discharged into water resources without proper treatment. This gives rise to the deterioration of water quality and imposes adverse effects on public health. Therefore, this study is aimed at removing Cr from electroplating wastewater using activated carbon produced from water hyacinth under a full factorial experimental design with three factors and three levels (pH,2,5 and 8, adsorbent dose 0.5,1and1.5 in 100 mL and contact time 30, 60 and120 min). A phosphoric acid solution of 37% was used to activate the carbon, which was then subjected to thermal decomposition for 15 min at 500 °C. The activated carbon was characterized by the presence of a high surface area (203.83 m2/g) of BET, cracking of adsorbent beads of SEM morphology, amorphous nature of XRD, and many functional groups of FTIR such as hydroxyl (3283 cm−1), alkane (2920 cm−1), nitrile (2114 cm−1) and aromatics (1613 cm−1). The minimum Cr adsorption performance of 15.6% was obtained whereas maximum removal of 90.4% was recorded at the experimental condition of pH 2, adsorbent dose of 1.5 g/100 mL, and contact time of 120 min at a fixed value of initial Cr concentration of 100 mg/L. Similarly, the maximum Cr removal from real electroplating wastewater was 81.2% at this optimum point. Langmuir's model best described the experimental value at R2 0.96 which implies the adsorption is chemically bonded, homogeneous, and monolayer. Pseudo-second-order model best fits with the experimental data with R2 value of 0.99. The adsorbent was regenerated for seven cycles and the removal efficiency decreased from 93.25% to 21.35%. Finally, this technology is promising to be scaled up to an industrial level.