Adsorption of arsenic and fluoride: Modeling of single and competitive adsorption systems

Abstract

The elevated co-occurrence of arsenic and fluoride in surface and groundwater poses risks to human health in many parts of the world. Using single and competitive batch equilibrium adsorption studies, this research focuses on As(V) and F adsorption by activated carbon and its modeling. BET, XRD, FESEM, EDS, and FTIR analysis were used to discern the structural characteristics of activated carbon. The influence of dosage, pH, and contact time were also investigated in single and simultaneous adsorption systems. The maximum adsorption capacity of activated carbon for arsenic and fluoride were found to be 3.58 mg/g and 2.32 mg/g, respectively. Kinetics studies indicated that pseudo-second-order kinetic model fit better than pseudo-first-order, Elovich, and intraparticle diffusion kinetic models. The non-linear regression analysis of Langmuir, Freundlich, Toth, Redlich Petersons, and Modified Langmuir Freundlich models was used to determine single-component asorption model parameters. Additionally, the simultaneous adsorption was rigorously modeled and compared using the Extended Langmuir (EL), Extended Langmuir Freundlich (ELF), Modified Competitive Langmuir (MCL), and Jeppu Amrutha Manipal Multicomponent (JAMM) isotherm models, and competitive mechanisms were interpreted for the simultaneous adsorption system. Further, the model performances were evaluated by statistical error analysis using the normalized average percentage error (NAPE), root mean square errors (RMSE), and the correlation coefficient (R2). According to the modeling results, single equilibrium data fitted better with the Modified Langmuir Freundlich isotherm model, with a higher R2 of 0.99 and lower NAPE values of 3.8 % and 1.28 % for As(V) and F, than other models. For the binary adsorption, the Extended Langmuir Freundlich isotherm model demonstrated excellent fit with lowest errors. All the competitive isotherm models fit the As(V) and F simultaneous sorption systems reasonably well. Furthermore, the research unveiled a nuanced hierarchy of isotherm fitting, with ELF > EL > MCL > JAMM in varying arsenic at a constant fluoride concentration, and ELF > JAMM > EL > MCL in varying fluoride at a constant arsenic concentrations. In addition, competitive studies divulged crucial insights into selective adsorption, as As(V) exhibits a pronounced adsorption selectivity over F on activated carbon. In essence, As(V) showed a more pronounced antagonistic behavior over F, whereas F exhibited a much lesser competitive behavior in the adsorption of arsenic.