Abstract

The retention of arsenate by four soils of Saskatchewan, Canada, and its relation to selected soil properties and anionic environments were studied. The data indicate that As retention by the soils at the dilute, As concentration range studied does not proceed through the precipitation of sparingly soluble arsenate compounds. Arsenate retention evidently proceeds through adsorption mechanisms. The adsorption maxima of the soils are not related to acidity and the contents of inorganic C, but are linearly related to amounts of ammonium oxalate-extractable Al and, to a lesser extent, to the contents of clay and ammonium oxalate-extractable Fe. Chloride, nitrate, and sulfate present at concentrations usually present in saline soils have little effect on the adsorption of As. Phosphate substantially suppresses As adsorption by the soils, and the extent of the suppression varies from soil to soil.

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