Adsorption Layer Characteristics of Mixed SDS/CnEOm Solutions. II. Dilational Viscoelasticity

Abstract

Bubble profile analysis tensiometry is used to study the surface rheological behavior of mixed SDS/C(12)EO(5) and SDS/C(14)EO(8) solutions. The experimental dependencies of the viscoelasticity modulus and phase angle are studied in a wide range of surfactant concentrations of the individual sodium dodecyl sulfate (SDS) and C(m)EO(n) solutions and SDS/C(n)EO(m) mixtures at various mixing ratios. By generating harmonic oscillations of the bubble area at low oscillation amplitudes, the relaxation behavior at oscillation frequencies between 0.005 and 0.2 Hz was studied. The applied theoretical approach to describe the dilational rheology of surfactant mixtures requires the specification of the equations of state of the mixed surface layer and the adsorption isotherm of the mixture's components. For the systems studied, the theoretical model considers different adsorption mechanisms for the different surfactants. In particular, the adsorption behavior of oxyethylated surfactants was described by the reorientation model (assumes two adsorption states of surfactant molecules with different molar areas), including an intrinsic compressibility of molecules in the state of minimal area. For the SDS component, the adsorption was assumed to be governed by the Frumkin model, which also accounts for the intrinsic compressibility. Satisfactory agreement between experimental data and theoretical calculations of the viscoelasticity modulus and the phase angle is obtained.