Abstract
The adsorption energy distribution functions for nitrogen and argon adsorbed on heterogeneous surfaces are calculated. These distributions are obtained by the least-squares method. The calculated monolayer capacity is proposed as a test of the goodness of the adsorption energy distribution function. Model surfaces are constructed using Bernal's model, and the corresponding adsorption isotherms are generated through grand canonical Monte Carlo computer simulations. The distributions obtained from adsorption isotherms are compared with those obtained from energy maps.
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