Adsorption-electrochemical mediated precipitation for phosphorus recovery from sludge filter wastewater with a lanthanum-modified cellulose sponge filter

Abstract

In this study, the sludge filter wastewater is confirmed to investigate the effects of adsorption-electrochemical mediated precipitation (EMP) driven phosphorus recovery on the basis of lanthanum-modified cellulose sponge filter (LCLM) material. The adsorption-EMP method relies on in situ recovery phosphate (P) from the used desorption agent (NaOH-NaCl binary solution) via the formation of Ca5(PO4)3OH all while preserving the alkalinity of the desorption agents which benefited long-term application. The lanthanum content of LCLM was 9.0 mg/g, and the adsorption capacity reached 226.1 ± 15.2 mg P/g La at an equilibrium concentration of 3.9 mg P/L. After adsorption, 55.7 % of P was recovered, and the corresponding alkalinity increased from 1.9 mmol/L to 2.2 mmol/L. Adsorption mechanism analysis revealed that the high lanthanum usage of LCLM was attributed to the synergistic effect of the lattice oxygen of LaO and LaPO4·0.5H2O crystallite formation. Additionally, the Ca5(PO4)3OH was found precipitated in the precipitation in the cathode chamber (P-CC) rather than on the surface/section of cation exchange membrane (CEM) and cathode indicating that the P recovery process was controlled by the saturation of CaP species in the EMP system and the electromigration effect. These findings present a new strategy to promote the effective utilization of rare earth elements for P adsorption and demonstrate the potential application of adsorption-EMP systems in dephosphorization for wastewater treatment.