Abstract
ABSTRACT In this work, the adsorption characteristics, including adsorption kinetic, isotherm and thermodynamics of chloramphenicol (CAP) onto powdered activated carbon (PAC), were carried out, and the feasibility of using ultrasound to regenerate saturated PAC in aqueous solution was evaluated. The adsorption results demonstrated that the adsorption mechanism was a complex process including surface adsorption, external liquid membrane diffusion and intraparticle diffusion as well, and the adsorption process was endothermic and non-spontaneous. The optimal conditions for PAC regeneration were as follows: acoustic density of 0.36 W/mL, saturated carbon dosage of 1.0 g/L and pH value of 10.36. The analysis of thermogravimetric analysis (TGA), Fourier transform infrared spectrometry (FTIR), Brunauer–Emmett–Teller (BET) surface area, pore size distribution and scanning electron microscopy (SEM) of PAC samples revealed that ultrasound mainly acted on surface functionalities, meso-pores and macro-pores of PAC through hydroxyl radical oxidization, high-pressure shock waves and high-speed microjets due to cavitation effect. This study highlighted that ultrasound could be efficiently desorbing CAP from saturated PAC. Practical applications of this method for PAC regeneration with complex natural matrices under environmentally realistic conditions were conducted and the adsorption capacity of the regenerated PAC decreased.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
