Adsorption Behavior of Different Components of a Polymer/Surfactant Composite Control System along an Injection-Production Channel in Sand Conglomerate Reservoirs.

Abstract

Sandy conglomerate reservoirs have become an important replacement area for unconventional energy to increase reserves and production. The polymer/surfactant composite control flooding system can effectively alleviate the water flooding front breakthrough caused by the interlayer or plane heterogeneity of the sand conglomerate reservoir and is an effective production method to reduce the water cutoff of the well and increase the oil recovery. In the process of controlling the oil displacement process of the system, the chromatographic separation effect was found due to the different viscosities of each component and the adsorption difference between the components and the rock, which weakened the development effect of the reservoir. It is necessary to study the adsorption law of each component of the complex controlled displacement system along the injection-production channel in the sand conglomerate reservoir. In this study, the microstructure and mineral composition of sandy conglomerates were determined by scanning electron microscopy and X-ray diffraction tests. The main particle size distribution was counted through a rock particle sieving experiment. A new characterization method called the large-size core physical model was used. The composite control system of sulfonate and betaine was used as the surfactant component, and the adsorption degree of each component in the displacement process was analyzed. The experimental results showed that the mass fraction of the sandy conglomerate increased with the decrease in particle size. The particles with a size of less than 0.08 mm account for a relatively high proportion, with a mass fraction of 60%. The content of brittle minerals, such as quartz and feldspar, in the glutenite was relatively high, and micrometer-sized pores and fractures were developed. The main factors affecting the viscosity of the composite system were the concentration and molecular weight of the polymer. The increase of injection volume of the flooding system is conducive to the maintenance of ultralow interfacial tension migration to the deep core. In the displacement process, when the polymer molecular chain was cut to a certain extent, the effect of throat shear was also slowed due to the short molecular chain. However, the shortened polymer molecules were more easily adsorbed on the surface of rock particles and the adsorption rate increased. The adsorption capacity of each component gradually decreased with the increase of the injection volume and injection concentration. The relative content of the composite control system and crude oil affects the type of emulsion, which undergoes a corresponding transformation during the driving process from a water-in-oil emulsion to an oil-in-water one. The research results of this paper enrich the mechanism of enhancing oil recovery of sand conglomerate reservoirs by polymer-surfactant composite regulation technology.